The first meeting of the joint UK-EU committee, to discuss the implementation of the withdrawal agreement, is due to take place by video conference on Monday, with Mr Gove facing European Commission Vice-President Maros Sefcovic.
A spokesman for Prime Minister Boris Johnson said the talks would “oversee the implementation, application and interpretation of the withdrawal agreement and will seek to resolve any issues that may arise from it”.
Mr Johnson announced on Friday that he had contracted coronavirus but was continuing to work in self-isolation.
Brexit happened on 31 January after Mr Johnson’s Conservatives won the general election by a landslide.
This ended more than three years of Parliamentary dispute and implemented the result of the 2016 referendum, in which 52% of UK voters chose not to stay in the EU.